EnergyAE / Knowledge Base

Refrigerants

Overview of refrigerants used in HPWHs — comparative properties, GWP, and detailed pages for CO₂, R290, and R-1234yf.

Refrigerant choice directly affects HPWH performance, cost, safety, and environmental impact. In the past, synthetic refrigerants (R134a, R410A) were standard, but the industry has shifted toward natural, low-GWP alternatives — particularly CO₂ (R744) and propane (R290).

No refrigerant perfectly balances thermal efficiency, safety, cost, and environmental impact. The table below summarises the most common options.

Detailed pages: CO₂ (R744) · Propane (R290) · HFO R-1234yf

The table below compares the most common refrigerants.

RefrigerantProsConsGWP
CO2 (R744)Quiet operation. Highly efficient. Higher outlet temperature up to 90degC.Higher upfront manufacturing costs. Safety concerns (high pressure) may require additional precautions.1
Propane (R290)Low manufacturing costs. Widely available raw materials. Good thermal efficiency.Highly flammable, necessitating stringent safety measures during production and use.3
R32Relatively low manufacturing cost.Limited availability of raw materials may impact production. Mild flammability can pose risks. Maximum 60degC.675
R1234yfIncreasing availability globally.Higher manufacturing costs compared to some alternatives. Mild flammability.4
R134aEstablished manufacturing capabilities contribute to lower costs.High GWP, being phased out from July 20241430
R410AWidely used in air conditioning and heat pump systems.High GWP, being phased out from July 20242088